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Trends in the monitoring of legacy and emerging organic pollutants in protected areas
Institution:1. Departamento de Desarrollo Tecnológico – DDT, Centro Universitario Regional del Este (CURE), Universidad de la República, Ruta 9 y Ruta 15, 27000 Rocha, Uruguay;2. Graduate Program in Chemistry, Facultad de Química, Universidad de la República, Uruguay;3. Departamento de Química del Litoral, CENUR Litoral Norte, Universidad de la República, Ruta 3 Km 363, 60000 Paysandú, Uruguay;4. Instituto de Medicina y Biología Experimental de Cuyo (IMBECU, CCT-CONICET), Mendoza 5500, Argentina;5. GEMA, Center for Genomics, Ecology & Environment, Universidad Mayor, Camino La Pirámide, 5750 Huechuraba, Santiago, Chile
Abstract:Protected Areas (PAs) are locations for conservation, internationally recognized for their natural, ecological, and/or cultural values. Human presence in PAs is generally limited to minimal or banned exploitation of natural resources. However, different threats to PAs are evident as a result of short and long-range transport of organic pollutants of legacy and emerging concern. There has been a shift of interest in legacy pollutants such as persistent organic pollutants (POPs) to emerging compounds, resulting in a need for improved monitoring strategies in PAs. Here, we highlight the main advances in environmental analytical chemistry for legacy and emerging pollution monitoring in PAs. Trends in sampling, sample preparation and instrumental determination of multiclass organic pollutants in biotic and abiotic matrices are presented and discussed. Here, we considered the most relevant and recent literature regarding organic pollutants in PAs from terrestrial to aquatic landscapes collected within 2015 to the present time frame.
Keywords:Protected Areas  Global Pollution  POPs  Emerging Contaminants  Mass spectrometry
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