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| Synthesis of Diethyl Oxalate by a Coupling—Regeneration Reaction of Carbon Monoxide | |
| 引用本文： | FandongMeng GenhuiXu 等. Synthesis of Diethyl Oxalate by a Coupling—Regeneration Reaction of Carbon Monoxide[J]. 天然气化学杂志, 2002, 11(1): 57-62 |
| 作者姓名： | FandongMeng GenhuiXu 等 |
| 作者单位： | SchoolofChemicalEngineeringandTechnology,TianjinUniversity,Tianjin300072,China |
| 摘 要： | This article describes a process for the synthesis of diethyl oxalate by a copling reaction of carbon monoxide,catalyzed by palladium in the presence of ethyl nitrite ,The kinetics and mechanism of the coupling and regeneration reaction are also discussed ,This paper presents the results of a scale-up test of the catalyst and the process based on an a priori computer simulation. |
| 关 键 词： | 二乙基草酸 一氧化碳 合成 动力学 |
Synthesis of Diethyl Oxalate by a Coupling-Regeneration Reaction of Carbon Monoxide |
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| Fandong Meng,Genhui Xu,Baowei Wang,Xinbin Ma. Synthesis of Diethyl Oxalate by a Coupling-Regeneration Reaction of Carbon Monoxide[J]. Journal of Natural Gas Chemistry, 2002, 11(1): 57-62 | |
| Authors: | Fandong Meng Genhui Xu Baowei Wang Xinbin Ma |
| Affiliation: | 1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China |
| Abstract: | This article describes a process for the synthesis of diethyl oxalate by a coupling reaction ofcarbon monoxide, catalyzed by palladium in the presence of ethyl nitrite. The kinetics and mechanism ofthe coupling and regeneration reaction are also discussed. This paper presents the results of a scale-uptest of the catalyst and the process based on an a priori computer simulation. |
| Keywords: | CO coupling diethyl oxalate kinetics and mechanism simulation scale-up test |
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