| Abstract: | We consider two identical, parallel, infinitely long solid cylinders at a given separation, lying flat on a plane oil/water interface and both immersed to the same extent in the oil and water phases. The part of the surface of each cylinder in contact with the aqueous phase is charged, forming an electric double layer in a symmetrical aqueous binary electrolyte. The electrical potential in the overlapping electric double layers in the aqueous phase satisfies the Poisson-Boltzmann equation. The potentials within the uncharged interiors of the solid cylinders and in the oil phase satisfy Laplace's equation. The equations for the three potentials are solved simultaneously using the finite element method with Galerkin weighted residuals. The double-layer interaction per unit length of the cylinders is then calculated. Of the numerical results obtained, three deserve special mention. First, a short-range double-layer repulsion, decaying exponentially with separation between the two cylinders, acts through the aqueous electrolyte medium, whereas in the case of an uncharged oil/water interface a weaker, but much longer-ranging, repulsive interaction acts through the oil medium. Second, reasonable estimates of the short-range interaction between cylinders in a planar interface can be obtained from the Derjaguin approximation for thin double layers. Third, in addition to the repulsive force between the cylinders parallel to the oil/water interface, a force normal to the interface acts on the cylinders in the direction of the aqueous electrolyte phase. |
