| 三(邻甲基苄基)氯化锡和二(对甲基苄基)二氯化锡的合成和晶体结构 |
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| 引用本文： | 张复兴,邝代治,王剑秋,冯泳兰,陈志敏,曾荣英.三(邻甲基苄基)氯化锡和二(对甲基苄基)二氯化锡的合成和晶体结构[J].无机化学学报,2006,22(7):1246-1250. |
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| 作者姓名： | 张复兴 邝代治 王剑秋 冯泳兰 陈志敏 曾荣英 |
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| 作者单位： | 衡阳师范学院化学与材料科学系,衡阳,421008 |
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| 基金项目： | 浙江省湖州市自然科学基金;湖南省衡阳市科技局资助项目 |
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| 摘 要： | 将邻甲基氯苄和对甲基氯苄在适当的溶剂中与锡粉反应，合成了三(邻甲基苄基)氯化锡1和二(对甲基苄基)二氯化锡2，用X射线衍射方法测定了化合物的晶体结构。化合物(1)的晶体属三方晶系，空间群为R3，晶体学参数：a=1.329 36(8) nm，b=1.329 36(8) nm，c=2.147 0(3) nm，α=β=90°，γ=120°，V=3.285 8(5) nm3，Z=6，Dc=1.424 g·cm-3，μ(Mo Kα)=12.93 cm-1，F(000)=1 428，R1=0.037 1，wR=0.110 2。化合物2的晶体属单斜晶系，空间群为C2/c，晶体学参数：a=2.850 4(3) nm，b=0.491 23(5) nm，c=1.215 32(12) nm，β=112.517(2)°，V=1.571 9(3) nm3，Z=4，Dc=1.690 g·cm-3，μ(Mo Kα)=19.49 cm-1，F(000)=792，R1=0.038 0，wR2=0.109 4；中心锡原子为畸变四面体配位构型。
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| 关 键 词： | 三(邻甲基苄基)氯化锡 二(对甲基苄基)二氯化锡 合成 晶体结构 |
| 文章编号： | 1001-4861(2006)07-1246-05 |
| 收稿时间： | 2006-02-18 |
| 修稿时间： | 2006-04-20 |
Synthesis and Crystal Structure of the Tri(o-methylbenzyl)tin Chloride and the Bis( p-methylbenzyl)tin Dichloride |
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| ZHANG Fu-Xing,KUANG Dai-Zhi,WANG Jian-Qiu,FENG Yong-Lan,CHEN Zhi-Ming and ZENG Rong-Ying.Synthesis and Crystal Structure of the Tri(o-methylbenzyl)tin Chloride and the Bis( p-methylbenzyl)tin Dichloride[J].Chinese Journal of Inorganic Chemistry,2006,22(7):1246-1250. |
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| Authors: | ZHANG Fu-Xing KUANG Dai-Zhi WANG Jian-Qiu FENG Yong-Lan CHEN Zhi-Ming and ZENG Rong-Ying |
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| Institution: | Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008 and Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008 |
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| Abstract: | |
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| Keywords: | tri(o-methylbenzyl)tin chloride bis(p-methylbenzyl)tin dichloride synthesis crystal structure |
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