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Direct electrochemistry of an [FeFe]-hydrogenase on a TiO2 electrode
Authors:Morra Simone  Valetti Francesca  Sadeghi Sheila J  King Paul W  Meyer Toby  Gilardi Gianfranco
Institution:Department of Human and Animal Biology, University of Torino, Torino, Italy.
Abstract:FeFe]-hydrogenases are efficient natural catalysts that can be exploited for hydrogen production. Immobilization of the recombinant FeFe]-hydrogenase CaHydA was achieved for the first time on an anatase TiO(2) electrode. The enzyme is able to interact and exchange electrons with the electrode and to catalyze hydrogen production with an efficiency of 70%.
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