| 多力响应基团聚合物合成的研究进展 |
| |
| 引用本文： | 邓亚奎,袁媛,陈于蓝.多力响应基团聚合物合成的研究进展[J].高等学校化学学报,2020,41(9):1956. |
| |
| 作者姓名： | 邓亚奎 袁媛 陈于蓝 |
| |
| 作者单位： | 天津大学分子光电科学天津市重点实验室, 天津 300354 |
| |
| 基金项目： | 国家自然科学基金(批准号(21975178);21734006)资助 |
| |
| 摘 要： | 多力响应基团聚合物(MMPs)的设计与合成为高灵敏地观察和定量力化学转变及高效利用机械能提供了新机遇, 推动了聚合物力化学的发展. 本文主要介绍了后聚合改性、 逐步聚合、 开环易位聚合和活性/可控自由基聚合等4种MMPs的合成方法, 分别对这些方法的特点、 优势和适用体系进行了论述, 期望为新型机械力响应性聚合物的制备和应用提供新思路.
|
| 关 键 词： | 多力响应基团聚合物 后聚合改性 逐步聚合 开环易位聚合 活性/可控自由基聚合 |
| 收稿时间： | 2020-06-01 |
Recent Advances in the Synthesis of Multi-Mechanophore Polymers |
| |
| DENG Yakui,YUAN Yuan,CHEN Yulan.Recent Advances in the Synthesis of Multi-Mechanophore Polymers[J].Chemical Research In Chinese Universities,2020,41(9):1956. |
| |
| Authors: | DENG Yakui YUAN Yuan CHEN Yulan |
| |
| Institution: | Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Tianjin University, Tianjin 300354, China |
| |
| Abstract: | The design and synthesis of multi-mechanophore polymers(MMPs) have provided great opportunities for observing, quantifying, and exploiting mechanochemical transformations, and thus promoted the development of polymer mechanochemistry. In this contribution, we make an overview of representative synthetic methodologies for MMPs, including post-polymerization modification, step-growth polymerization, ring-opening metathesis polymerization, and living/controlled radical polymerization. The characteristics, advantages and applicable systems of these methods are discussed, respectively. The aim of this review is to open a new avenue towards the synthesis and applications of diverse mechano-responsive polymers and materials. |
| |
| Keywords: | Multi-mechanophore polymer Post-polymerization modification Step-growth polymerization Ring-opening metathesis polymerization Living/controlled radical polymerization |
|
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
| 点击此处可从《高等学校化学学报》下载免费的PDF全文 |
