| 稀土-钛氧簇合物的研究进展 |
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| 引用本文： | 李观俊,龙腊生,孔祥建,郑兰荪.稀土-钛氧簇合物的研究进展[J].高等学校化学学报,2020,41(12):2577. |
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| 作者姓名： | 李观俊 龙腊生 孔祥建 郑兰荪 |
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| 作者单位： | 厦门大学化学化工学院化学系, 固体表面物理化学国家重点实验室, 能源材料化学协同创新中心, 厦门 361005 |
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| 基金项目： | 国家自然科学基金(批准号(21871224);21673184, 21721001)资助 |
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| 摘 要： | 稀土-钛氧簇合物作为团簇化学的一个新分支, 不但结合了稀土和钛离子的特性, 而且由于二者的协同效应而表现出优异的光、 电、 磁和催化性能.本文综合评述了不同配体稀土-钛氧簇合物的合成与结构, 介绍了稀土-钛氧簇合物的代表性成果, 并对其合成策略和发展前景进行了总结和展望.
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| 关 键 词： | 稀土-钛氧簇合物 合成 结构 荧光 光催化 |
| 收稿时间： | 2020-07-01 |
Recent Advances in Lanthanide-titanium-oxo Clusters |
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| LI Guanjun,LONG Lasheng,KONG Xiangjian,ZHENG Lansun.Recent Advances in Lanthanide-titanium-oxo Clusters[J].Chemical Research In Chinese Universities,2020,41(12):2577. |
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| Authors: | LI Guanjun LONG Lasheng KONG Xiangjian ZHENG Lansun |
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| Institution: | Collaborative Innovation Center of Chemistry for Energy Materials，State Key Laboratory of Physical Chemistry of Solid Surface，Department of Chemistry，College of Chemistry and Chemical Engineering，Xiamen University，Xiamen 361005，China |
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| Abstract: | As a new branch of cluster chemistry， lanthanide-titanium-oxo clusters not only integrate the cha-racteristics of lanthanide and titanium ions， but also often show a synergistic effect of the two elements， so they usually have excellent optical， electoral， magnetic and catalytic properties. The lanthanide-titanium-oxo cluters attract more attention because its accurate structure model is more conducive to understand the relationship between structure and activity. In this paper， the synthesis and structures of lanthanide-titanium-oxo clusters are outlined based on different ligands and the representative properties are introduced. The synthetic strategies and development prospects of lanthanide-titanium-oxo clusters are prospected. It is hoped that this review can provide insight into future research on lanthanide-titanium-oxo clusters. |
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| Keywords: | Lanthanide-titanium-oxo cluster Synthesis Structure Luminescence Photocatalysis |
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