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Synthesis and Structure of [4.5.5.5]Fenestranes ( = tetracyclo[5.4.1.04, 12.09, 12]dodecanes)
Authors:Daniel Hirschi  Wolfgang Luef  Peter Gerber  Reinhart Keese
Abstract:
The preparation and the X-ray structure analysis of cis, trans, cis, cis-10-hydroxy-[4.5.5.5]fenestrane-1-methanol ( 8b ) is reported. The measured bond angles and bond lengths of the central C(C)4 fragment are better reproduced by calculations with the AM 1 than by the MNDO method.
Keywords:
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