Abstract: | The crystallization in GeO2-NaCl-H2O, CdO-NaOH(NaCl)–H2O. CdO–GeO2–H2O, CdO–GeO2–NaOH (NaCl)–H2O systems investigated under hydrothermal conditions depending on the initial ratio of CdO and GeO2 oxides in starting material and solvent concentration. Single crystals of six Cd-germanates and five accessory compounds are obtained. The influence of the mineralizer on Cd-germanates crystallization and the chemism of the interaction of the charge components and the solvent are discussed. |