Conformation of diethylglyoxime in uranyl complexes |
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| Authors: | A. G. Beirakhov I. M. Orlova A. V. Rotov E. G. Il’in L. V. Goeva M. D. Surazhskaya A. V. Churakov Yu. N. Mikhailov |
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| Affiliation: | 1.Kurnakov Institute of General and Inorganic Chemistry,Russian Academy of Sciences,Moscow,Russia |
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| Abstract: | ![]()
New complexes of uranyl with diethylglyoxime have been synthesized and studied. A feature of these complexes is the tetradentate bridging coordination of the ligand in both cis- and trans-conformations. The structure of organic ligand C6H12N2O2 and binuclear complex (CN3H6)4[(UO2)2(C6H10N2O2)(CO3)(C2O4)2] ? H2O have been determined by X-ray diffraction. |
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