Kinetics of dimerization of 2-alkylthiopropenals |
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| Authors: | N. A. Keiko L. G. Stepanova Yu. A. Chuvashev L. I. Larina M. G. Voronkov |
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| Affiliation: | (1) Irkuisk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033 Irkutsk, Russian Federation |
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| Abstract: | The rate constants for cyclodimerization of α-alkylthioacroleins were determined. They are two orders of magnitude higher than those for dimerization of α-alkoxyacroleins. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2020–2021, October, 1999. |
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| Keywords: | 2-alkylthiopropenals cyclodimerization reaction rate 2,5-dialkylthio-3,4-dihydro-2H-pyran-2-carbaldehydes the Diels-Alder reaction |
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