Synthesis and reactivity of triethylborane adduct of N-heterocyclic carbene: versatile synthons for synthesis of N-heterocyclic carbene complexes |
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| Authors: | Yamaguchi Yoshitaka Kashiwabara Taigo Ogata Kenichi Miura Yumiko Nakamura Yoshiyuki Kobayashi Kimiko Ito Takashi |
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| Affiliation: | Department of Materials Chemistry, Graduate School of Engineering, Yokohama National University, Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan. |
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| Abstract: | The reaction of an imidazolium salt with LiBEt(3)H afforded triethylborane adduct of imidazol-2-ylidene, which can act as a carbene precursor for the synthesis of a transition metal complex as well as a main group element complex. |
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