Oxidative nucleophilic substitution: transformation of alkylboronic derivatives |
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| Authors: | Clé ment CazorlaEstelle Mé tay,Marc Lemaire |
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| Affiliation: | Laboratoire de CAtalyse, SYnthèse et ENvironnement, Université de Lyon, UCBL, ICBMS, UMR-CNRS 5246, Campus de la Doua, Bâtiment Curien-CPE, 3° étage, 43Boulevard du 11 Novembre 1918, 69622 Villeurbanne Cedex, France |
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| Abstract: | ![]()
An efficient amidation reaction is described in this paper. Potassium alkyltrifluoroborate salts can be transforming to amides from nitriles in the presence of copper acetate and boron trifluoride. An extension of this reaction allowed the formation of amines, ethers, and C-C bond. |
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| Keywords: | Copper acetate Alkylboronic Boron trifluoride Oxidative nucleophilic substitution Amidation |
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