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(C2N2H10)2Mg(HP2O7)2·2H2O synthesis and crystal structure |
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| Authors: | Rachid Essehli Brahim El Bali Mohammed Lachkar Michael Dusek Fejfarova Karla Michael Bolte |
| Institution: | 1. Laboratoire d’Ingénierie des Matériaux Organométalliques et Moléculaires, Département de Chimie, Faculté des Sciences, Université Sidi Mohamed Ben Abdellah, B.P. 1796 (Fès-Atlas), 30000, Fès, Morocco 2. Laboratory of Mineral Solid and Analytical Chemistry “LMSAC,” Department of Chemistry, Faculty of Sciences, University Mohamed I, Po. Box 624, 60000, Oujda, Morocco 3. Institute of Physics, Na Slovance 2, 182 21, Praha 8, Czech Republic 4. Institut für Anorganische Chemie, J. W. Goethe-Universit?t Frankfurt, Max-von-Laue-Str. 7, 60438, Frankfurt/Main,, Germany |
| Abstract: | (C2N2H10)2Mg(HP2O7)2·2H2O, is a new inorganic organic hybrid structure. It has been synthetized using wet chemistry. Its crystal structure consists of cis- and trans-edge sharing MgO4(H2O)2] octahedra resulting in chains, which are linked via HP2O7] units to form Mg(HP2O7)2(H2O)2]4− layers. The Mg2+ cations and the ethylendiammonium cations are located on centers of inversion. The ethylendiammonium cations are alternately located in the interlayer space. The cohesion of the crystal is well ensured by coulombic interactions between anions and cations and by several hydrogen bonds. The diphosphate anion shows an eclipsed conformation. |
| Keywords: | Magnesium Diphosphate Layered structure |
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