Methyl benzothiazol-2-yliminotrifluoropyruvates in the Diels-Alder aza-reaction with cyclopentadiene and cyanoamines |
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| Authors: | V B Sokolov A Yu Aksinenko |
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| Institution: | 1. Institute of Physiologically Active Substances, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia
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| Abstract: | Methyl trifluoropyruvate benzothiazol-2-ylimines exhibit both a heterodiene and a dienophile properties in the Diels-Alder aza-reaction with cyclopentadiene and cyanoamines, leading to the formation of 4-substituted 2-trifluoromethyl-2H-1,3,5]triazine2,1-b]1,3]benzothiazole and 2-benzothiazol-2-yl-3-trifluoromethyl-2-azabicyclo2.2.1]hept-5-ene, respectively. |
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