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Spectrophotometric determination of chloride,bromide, and iodide with an improved mercury-iron-thiocyanate method
Authors:Wolfgang J Kirsten  Inger Lindholm-Franzén
Institution:Department of Chemistry, Swedish University of Agricultural Sciences, S-750 07 Uppsala, Sweden
Abstract:Stable reagents for the spectrophotometric mercury-iron-thiocyanate method for the determination of halide have been developed. The molar absorptivity for concentrations up to 170 μmole/liter of halide is for chloride 3.4 × 103, for bromide 3.9 × 103, and for iodide 4.0 × 103. Above this concentration there is a slight decrease of the absorptivity for chloride and a slight increase for bromide and iodide.
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