Tetranuclear nickel(II) complexes with genuine mu3-1,1,3 and mu4-1,1,3,3 azide bridges |
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Authors: | Meyer Franc Kircher Peter Pritzkow Hans |
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Affiliation: | Institut für Anorganische Chemie, Georg-August-Universit?t, Tammannstrasse 4, D-37077 G?ttingen, Germany. franc.meyer@chemie.uni-goettingen.de |
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Abstract: | Unique tetranickel(II) complexes have been synthesized which incorporate genuine mu3-1,1,3 or mu4-1,1,3,3 bridging azido ligands. Identification of two distinct isomeric mu4-1,1,3,3 binding modes confirms the structural flexibility of the quadruply bridging azide. |
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