The first example of enantioselective isocyanosilylation of meso epoxides with TMSCN catalyzed by novel chiral organogallium and indium complexes |
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| Authors: | Zhu Chengjian Yuan Fang Gua Weijin Pan Yi |
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| Institution: | Department of Chemistry, Nanjing University, Nanjing 210093, China. cjzhu@netra.nju.edu.cn |
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| Abstract: | The desymmetrization ring opening of meso epoxides using trimethylsilyl cyanide catalyzed by organogallium and indium complexes with binaphthol monoether derivatives as chiral ligands gave beta-isocyanohydrins with moderate to excellent enantioselectivities of up to 95% ee. |
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