Reversible C-C bond formation: solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium,and its solution state retro-aldol dissociation |
| |
| Authors: | Ball Lee-Jon Dickie Anthony P Mair Francis S Middleton David A Pritchard Robin G |
| |
| Affiliation: | Department of Chemistry, UMIST, PO Box 88, Manchester, UK M60 1QD. |
| |
| Abstract: | ![]()
Analysis of crystals of the lithium complex of the tripodal ligand formed upon addition of adamantanone to a 1,5 diazapentadienyllithium complex reveals a long C-C bond which ruptures upon dissolution in non-co-ordinating solvents. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
