| 精氨酸水相催化直接羟醛缩合反应：一个 环境友好的反应体系 |
| |
| 引用本文： | 彭以元a,b 王琦a 何家骐a 程津培a. 精氨酸水相催化直接羟醛缩合反应：一个 环境友好的反应体系[J]. 中国化学, 2008, 26(8): 1454-1460. DOI: 10.1002/cjoc.200890264 |
| |
| 作者姓名： | 彭以元a b 王琦a 何家骐a 程津培a |
| |
| 作者单位： | a 南开大学化学院, 南开大学元素有机重点实验室,中国天津 300071 ;b 江西省绿色化学重点实验室, 江西师范大学化学系, 中国江西330022 ; |
| |
| 摘 要： | 本文研究了精氨酸在水中催化羟醛缩合反应，结果表明：精氨酸在水相中可作为一种高效的有机小分子催化剂，催化缺电子芳香醛与酮间的反应，催化剂精氨酸可以回收重复使用10次，催化活性基本不变。
|
| 关 键 词： | 精氨酸、有机小分子催化 羟醛缩合反应 环境友好反应 |
| 收稿时间： | 2008-01-20 |
| 修稿时间： | 2008-03-06 |
Arginine Catalyzed Direct Aldol Reactions in Pure Water: An Environmentally Friendly Reaction System |
| |
| Yi‐Yuan PENG,Qi WANG,Jia‐Qi HE,Jin‐Pei CHENG. Arginine Catalyzed Direct Aldol Reactions in Pure Water: An Environmentally Friendly Reaction System[J]. Chinese Journal of Chemistry, 2008, 26(8): 1454-1460. DOI: 10.1002/cjoc.200890264 |
| |
| Authors: | Yi‐Yuan PENG Qi WANG Jia‐Qi HE Jin‐Pei CHENG |
| |
| Affiliation: | 1. State Key Laboratory of Elemento‐organic Chemistry, Department of Chemistry, Nankai University, Tianjin 300071, China;2. Jiangxi Key Laboratory of Green Chemistry, Department of Chemistry, Jiangxi Normal University, Nanchang, Jiangxi 330027, China |
| |
| Abstract: | The first investigation of arginine catalyzed direct aldol reactions demonstrated that arginine could serve as an efficient small organo‐catalyst for the reactions of the electron deficient benzaldehydes with ketones in pure water and could be reused ten times without substantial loss of its activity. |
| |
| Keywords: | arginine organocatalysis aldol reaction environmentally friendly reaction |
|
| 点击此处可从《中国化学》浏览原始摘要信息 |
|
点击此处可从《中国化学》下载全文 |
