Multi-temporal self-organizations in 1,3-O,O'-bis(dodecyl)calix[4]arene |
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| Authors: | Li Alexander D Q Marquez Manuel Guo Mingming |
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| Institution: | Department of Chemistry, Center for Materials Research Center, Washington State University, Pullman, WA 99164, USA. |
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| Abstract: | After heat erases the order in 1,3-O,O'-bis(dodecyl)calix4]arene, it self-organizes the phenyl units into a rigid calix bowl first at T2 = 111 degrees C, followed by the formation of all-trans alkyl chains at T1 = 62 degrees C, which eventually yields a stable cone-shaped structure at room temperature. |
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