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Synthesis and coordination chemistry of a water-soluble verdazyl radical. structures and magnetic properties of M(H2O)2(vdCO2)(2).2H2O (M = Co,Ni; vdCO2 = 1,5-dimethyl-6-oxo-verdazyl-3-carboxylate)
Authors:Barclay Tosha M  Hicks Robin G  Lemaire Martin T  Thompson Laurence K  Xu Zhiqiang
Institution:Department of Chemistry, North Harris College, Houston, Texas 77073, USA.
Abstract:The synthesis of a verdazyl radical with a carboxylate substituent renders the radical highly soluble in water, thereby permitting the aqueous synthesis of Ni(II) and Co(II) verdazyl complexes which have been structurally and magnetically characterized.
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