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Rotational polymorphism in 2-naphthalenethiol SAMs on Au(111)
Authors:Jiang Peng  Nion Aymeric  Marchenko Alexandr  Piot Luc  Fichou Denis
Affiliation:CEA-Saclay, LRC Nanostructures et Semi-Conducteurs Organiques CNRS-CEA-UPMC, SPCSI/DRECAM, 91191 Gif-sur-Yvette, France.
Abstract:We evidence by STM that 2-naphthalenethiol self-assembled monolayers formed at the n-tetradecane/Au(111) interface coexist as two structural phases which both possess molecules into two different orientations (standing and lying). Such a rotational polymorphism is observed and understood at the molecular level for the first time.
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