Rotational polymorphism in 2-naphthalenethiol SAMs on Au(111) |
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Authors: | Jiang Peng Nion Aymeric Marchenko Alexandr Piot Luc Fichou Denis |
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Affiliation: | CEA-Saclay, LRC Nanostructures et Semi-Conducteurs Organiques CNRS-CEA-UPMC, SPCSI/DRECAM, 91191 Gif-sur-Yvette, France. |
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Abstract: | We evidence by STM that 2-naphthalenethiol self-assembled monolayers formed at the n-tetradecane/Au(111) interface coexist as two structural phases which both possess molecules into two different orientations (standing and lying). Such a rotational polymorphism is observed and understood at the molecular level for the first time. |
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