Syntheses, Crystal Structures and Electrochemical Properties of Two Molybdophosphates |
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| Authors: | YU Yang YU Kai ZHOU Bai-Bin ZHAO Zhi-Feng SU Zhan-Hua |
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| Institution: | [1]Key Laboratory of Physical and Chemical Materials, College ofHeilongjiang Province, Harbin Normal University, Harbin 150025, China [2]Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150001, China |
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| Abstract: | Two molybdophosphate compounds,Ni(bim)3]2H2P2Mo5O23]·2H2O 1 and 2,2'-dipyridyl),have been synthesized under hydrothermal conditions and structurally characterized by elemental analysis,TG.and IR.The single-crystal X-ray analysis exhibits that 1 consists of one H2P2Mo5O23]4-,twoNi(bim)3]2+ cations and two lattice water molecules,while 2 is constructed from one sandwich-typeZnP4Mo6]anion modified by four Zn-bpy complexes and nine lattice water molecules.The electrochemical behaviors of compounds 1 and 2 have been studied in detail based on solid bulk modified carbon paste electrodes of compound(CPEs). |
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| Keywords: | molybdophosphates hydrothermal synthesis crystal structure electrochemical property |
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