Coordination-induced branched self-assembly of porphyrins bearing two redox-active phenylenediamine chains |
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| Authors: | Toru Amaya |
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| Affiliation: | Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan |
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| Abstract: | The porphyrins bearing two three-dimensionally regulated oligoaniline chains with terminal pyridyl groups were synthesized. The self-assembled branched polymer complex by introducing Zn(II) to the porphyrin was achieved in solution, which underwent dropcasting on the surface of mica to result in dome-like nanostructures. |
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| Keywords: | Porphyrin Oligoaniline π-Conjugated compound Self-assembly |
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