Hydroperoxides and aryl diazonium salts as reagents for the functionalization of non-activated olefins |
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| Authors: | Olga Blank Markus R Heinrich |
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| Institution: | a Organische Chemie 1, Technische Universität München, Lichtenbergstraße 4, 85747 Garching b. München, Germany
b Pharmazeutische Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg, Schuhstraße 19, 91052 Erlangen, Germany |
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| Abstract: | Hydroperoxides, olefins, and arenediazonium salts selectively combine to give azo compounds via an iron(II)-mediated three-component reaction. Starting with a fragmentation liberating acetic acid, the hydroperoxides act as radical source and the diazonium ions as nitrogen-centered radical scavengers. |
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| Keywords: | Radical reactions Hydroperoxides Olefin functionalization Arenediazonium salts |
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