Iodine as a versatile catalyst for the hydroalkylation of vinyl arenes with 1,3-diketones |
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Authors: | J.S. Yadav B.V. Subba Reddy T. Srinivasa Rao K. Bhavani A. Raju |
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Affiliation: | Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
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Abstract: | The vinyl arenes undergo smooth hydroalkylation with 1,3-diketones in the presence of 10 mol % of iodine to afford phenethyl diketones and ketoesters in good yields in short reaction times. The use of inexpensive and readily available molecular iodine makes this method quite simple, more convenient and practical. |
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Keywords: | Hydroalkylation Vinyl arenes Molecular iodine 1,3-Diketones |
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