Synthesis of azidochloromethane and azidobromomethane |
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| Authors: | Klaus Banert Young-Hyuk Joo Bernhard Walfort |
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| Institution: | a Chemnitz University of Technology, Organic Chemistry, Strasse der Nationen 62, 09111 Chemnitz, Germany
b Chemnitz University of Technology, Inorganic Chemistry, Strasse der Nationen 62, 09111 Chemnitz, Germany |
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| Abstract: | By treatment of tris(azidomethyl)amine with dry hydrogen halide, azidochloromethane and azidobromomethane were prepared. The former product, which is more stable than the latter, was isolated as a colorless liquid. The desired azidohalomethanes are intermediates in the nucleophilic substitution of dihalomethanes to generate diazidomethane but could not be detected in this transformation. |
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| Keywords: | Azides Hazardous compounds Nucleophilic substitution Triazoles |
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