Facile synthesis of benzofulvene derivatives from Baylis-Hillman adducts: In-mediated Barbier reaction combined with Pd(0)-catalyzed intramolecular Heck-elimination cascade |
| |
| Authors: | Ko Hoon Kim |
| |
| Affiliation: | Department of Chemistry and Institute of Basic Science, Chonnam National University, Gwangju 500-757, Republic of Korea |
| |
| Abstract: | ![]()
A facile synthesis of benzofulvene derivatives was carried out starting from the Baylis-Hillman adducts of 2-bromobenzaldehyde via the sequential bromination, In-mediated Barbier reaction with aldehyde, acetylation, Pd-catalyzed intramolecular Heck reaction, and the elimination of AcOH. |
| |
| Keywords: | Benzofulvenes Baylis-Hillman adducts Indium Palladium 1,4-Elimination |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
