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The generation of diazirinone: a computational study
Authors:Robert A. Moss  Ronald R. Sauers
Affiliation:Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, New Brunswick, NJ 08903, United States
Abstract:
Computational studies indicate that the reaction of p-nitrophenoxyfluorodiazirine with fluoride ion should generate diazirinone. However, fluoride ion also catalyzes the decomposition of diazirinone to carbon monoxide and nitrogen, so that the diazirinone is likely to be unstable to the conditions used to generate it.
Keywords:Diazirines   Calculations   Fluoride ion   Catalysis
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