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Adsorption Studies of Radionuclides and Toxic Metal Ions on a Modified Mesoporous Lanthanum(III) Silicate
Authors:Hamid Sepehrian  Syed Javad Ahmadi  Syed Waqif‐Husain  Ahmad Reza Zolfaghari‐Daryani  Mortaza Azadmousavi
Affiliation:1. Fax: 0098‐21‐82062539;2. NFCRS, Nuclear Science and Technology Research Institute, AEOI, P.O. Box 11365/8486, Tehran, Iran;3. Department of Chemistry, Faculty of Science, Science and Research Branch, Islamic Azad University, P.O. Box 14515‐775, Poonak‐Hesarak, Tehran, Iran;4. Faculty of Nuclear Engineering, University of Shahid Beheshti, Tehran, Iran
Abstract:
A new adsorbent, modified mesoporous lanthanum(III) silicate, has been prepared with various molar ratios of Si/La (10, 20, 40, 80) and cethyltrimethylammonium bromide (CTAB) as structure directing agent. XRD, nitrogen sorption, SEM, IR, thermogravimetry and sorption of radionuclides and toxic metal ions have been studied. The results show that adsorption amount of some element such as Pb(II) and Th(IV) has been increased significantly by incorporation of lanthanum ions in the framework of adsorbent. Separation of Co(II)‐Th(IV), Co(II)‐U(VI) and Mo(VI)‐U(VI) has been developed on columns of this adsorbent.
Keywords:mesoporous lanthanum(III) silicate  radionuclide  toxic metal ion  adsorption study
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