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Entropy‐Controlled Catalytic Asymmetric 1,4‐Type Friedel–Crafts Reaction of Phenols Using Conformationally Flexible Guanidine/Bisthiourea Organocatalyst
Authors:Dr. Yoshihiro Sohtome  Bongki Shin  Natsuko Horitsugi  Rika Takagi  Prof. Dr. Keiichi Noguchi  Prof. Dr. Kazuo Nagasawa
Affiliation:1. Department of Biotechnology and Life Science, Faculty of Technology, Tokyo University of Agriculture and Technology, 2‐24‐16 Naka‐cho, Koganei, Tokyo 184‐8588 (Japan), Fax: (+81)?42‐388‐7295;2. Instrumentation Analysis Center, Tokyo University of Agriculture and Technology, 2‐24‐16 Nakamachi, Koganei, Tokyo 184‐8588 (Japan)
Abstract:
Keywords:entropy  Friedel–  Crafts reaction  hydrogen bonds  organocatalysis  phenols
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