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Sensitive electrochemical sensor for hydrogen peroxide using Fe3O4 magnetic nanoparticles as a mimic for peroxidase |
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| Authors: | Zhanxia Zhang Hui Zhu Xiaolei Wang Xiurong Yang |
| Institution: | 1. State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Renmin Street 5625, Changchun, Jilin, 130022, China 2. Graduate School of the Chinese Academy of Sciences, Beijing, 100039, China |
| Abstract: | A sensor for hydrogen peroxide is described that is based on an indium tin oxide electrode modified with Fe3O4 magnetic nanoparticles which act as a mimic for the enzyme peroxidase and greatly improve the analytical performance of the sensor. The amperometric current is linearly related to the concentration of H2O2 in the range from 0.2 mM to 2 mM, the regression equation is y?=?-0.5–1.82x, the correlation coefficient is 0.998 (n?=?3), and the detection limit is 0.01 mM (S/N?=?3). The sensor exhibits favorable selectivity and excellent stability. Using the peroxidase mimic property of Fe3O4 magnetic nanoparticles (MNPs), a sensitive electrochemical method with favorable analytical performance for the determination of hydrogen peroxide (H2O2) was developed. |
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