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Synthesis and characterization of perfluorohexylated poly(3,4-ethylenedioxythiophene) |
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| Authors: | Liangbin Zuo Wei-Dong Meng Sen Zhang |
| Institution: | a College of Chemistry and Chemical Engineering, Donghua University, 1882 West Yanan Lu, Shanghai 200051, China b Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 354 Fenglin Lu, Shanghai 200032, China c Department of Chemistry, Fudan University, 220 Handan Lu, Shanghai 200043, China |
| Abstract: | The perfluorohexylated 3,4-ethylenedioxythiophene 5 was prepared via Mitsunobu reaction of perfluorohexylatyed diol 2 with diethyl 3,4-dihydroxythiophenedicarboxylate followed by decarboxylation. The polymerization of 5 was conducted with both oxidative chemical and electrochemical polymerizations. The polymers were characterized by cyclic voltammogram, UV, IR, TGA and DSC. |
| Keywords: | Perfluorohexylated poly(3 4-ethylenedioxythiophene) Oxidative chemical polymerization Electrochemical polymerization |
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