The lithiation studies of nanostructured tungsten oxide film prepared via electrochemical precipitation |
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Authors: | Hossein Farsi Zahra Barzgari |
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Affiliation: | 1. Department of Chemistry, University of Birjand, Birjand, Iran
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Abstract: | In this work, nanostructured tungsten oxide was electrodeposited by cyclic voltammetric technique onto a stainless steel surface. The structure and surface morphology of the resulting oxide film were characterized by means of X-ray diffraction, scanning probe microscopy, and scanning electron microscopy. The electrochemical intercalation of lithium into the nanostructured tungsten oxide was studied using cyclic voltammetry, galvanostatic charge–discharge curves, and electrochemical impedance spectroscopy in a liquid electrolyte consisting of 1 M LiClO4 in propylene carbonate. The as-deposited tungsten oxide indicated the capacity for electrochemical lithium insertion. The specific capacitance of 108.05 F?g?1 was obtained at the constant discharge density of 0.07 mA?cm?2. |
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