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Kinetic study and analytical application of the iodate-hypophosphite reaction in strongly acidic solutions
Authors:D.P. Nikolelis  M.I. Karayannis  E.V. Kordi  T.P. Hadjiioannou
Affiliation:Laboratory of Analytical Chemistry, University of Athens, AthensGreece
Abstract:
The iodate—hypophosphite reaction in strongly acidic solutions was studied spectrophotometrically. Reaction rate constants and the activation energy of the reaction are reported. A method for determining hypophosphite on the basis of this reaction is described. Hypophosphite in the range 0.06–4 mg (10-3–6·10-2 M) can be determined with a relative error and relative standard deviation of 2—3%.
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