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Investigation of emission properties of Tm3+:Y2O3 transparent ceramic
引用本文:易庆,Taiju Tsuboi,周圣明,Yosuke Nakai,林辉,腾浩.Investigation of emission properties of Tm3+:Y2O3 transparent ceramic[J].Chinese Optics Letters,2012(9):67-71.
作者姓名:易庆  Taiju Tsuboi  周圣明  Yosuke Nakai  林辉  腾浩
作者单位:Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences;Graduate University of Chinese Academy of Sciences;Faculty of Engineering, Kyoto Sangyo University
基金项目:supported by the National Natural Science Foundation of China (Nos. 51172254 and 60990311);the Special Funds for Major State Basic Research Project of China (No. 2011CB301900);the Science and Technology Commission of Shanghai Municipality (No.10JC1415700)
摘    要:A transparent and emitting ceramic of Y 2 O 3 doped with 6% Tm 3+ ions is fabricated by vacuum sintering with ZrO 2 . Absorption, photoluminescence (PL), and PL excitation (PLE) spectra are investigated in a spectral range of 200 to 2 100 nm at various temperatures between 296 and 12 K. Intense emission band appears at 450 to 465 nm in the visible range. Near-infrared emission bands are observed at 1 200 to 1 300 nm and 1 400 to 1 550 nm, with intense peaks at 1 270, 1 450, and 1 523 nm. The luminescence mechanisms and potential applications of the emissions are discussed with the help of Judd-Ofelt theory and PLE spectra.

关 键 词:透明陶瓷  Y2O3  发射特性  Judd-Ofelt理论  光谱范围  真空烧结  发光陶瓷  离子掺杂

Investigation of emission properties of Tm3+ :Y2 O3 transparent ceramic
Qing Yi,Taiju Tsuboi,Shengming Zhou,Yosuke Nakai,Hui Lin,and Hao Teng.Investigation of emission properties of Tm3+ :Y2 O3 transparent ceramic[J].中国光学快报(英文版),2012(9):67-71.
Authors:Qing Yi  Taiju Tsuboi  Shengming Zhou  Yosuke Nakai  Hui Lin  and Hao Teng
Institution:1 Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China 2 Faculty of Engineering, Kyoto Sangyo University, Kamigamo, Kita-ku, Kyoto 603-8555, Japan 3 Graduate University of Chinese Academy of Sciences, Beijing 100049, China
Abstract:A transparent and emitting ceramic of Y 2 O 3 doped with 6% Tm 3+ ions is fabricated by vacuum sintering with ZrO 2 . Absorption, photoluminescence (PL), and PL excitation (PLE) spectra are investigated in a spectral range of 200 to 2 100 nm at various temperatures between 296 and 12 K. Intense emission band appears at 450 to 465 nm in the visible range. Near-infrared emission bands are observed at 1 200 to 1 300 nm and 1 400 to 1 550 nm, with intense peaks at 1 270, 1 450, and 1 523 nm. The luminescence mechanisms and potential applications of the emissions are discussed with the help of Judd-Ofelt theory and PLE spectra.
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