Polarity and polarizability of alkoxyacetylenes |
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Authors: | A. A. Bredikhin V. L. Polushina A. N. Vereshchagin |
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Affiliation: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR |
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Abstract: | Conclusions The dipole moment of the Csp-O bond in alkoxyacetylenes is 1.3 D and is directed toward the carbon atom. The values for the major semiaxes in the polarizability ellipsoid of the HC=CO fragment are bL=4.60 and bT=bv=2.77 Å3.Translated from Izvestiya Akaderaii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1198–1200, May, 1986. |
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