Spectrophotometric and Nuclear Magnetic Resonance Study of Temperature- and Pressure-induced Changes in the Intimate Solvation of Neodymium (III) in N,N-Dimethylformamide and Trimethylphosphate |
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| Authors: | Dino L Pisaniello Peter J Nichols Yves Ducommun Andr E Merhach |
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| Institution: | Dino L. Pisaniello,Peter J. Nichols,Yves Ducommun,André E. Merhach |
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| Abstract: | The temperature- and pressure-dependent equilibria for the addition of an extra N, N-dimethylforrnamide (DMF) or trimethylphosphate (TMP) ligand onto Nd (DMF)8]3+- and Nd(TMP)6]3+-species respectively have been measured by visible spectrophotometry. Complementary NMR. studies on other lanthanide ions show a gradual shift in preference for the lower coordination number across the lanthanide series. |
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