Note sur le mécanisme réactionnel de la transposition de Dimroth. Une étude ab initio |
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Authors: | Mint Tho Nguyen Georges Leroy Michel Sana Jos Elguero |
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Institution: | Mint Tho Nguyen,Georges Leroy,Michel Sana,José Elguero |
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Abstract: | An ab initio study of the Dimorth rerarrangement of the -amino-1,2,3,4-tetrazole leads to the conclusion teht in vapour phase the rate determining step is not the ring-chain isomerism, but is either the Z-E iomerism around the C?N double bond or the 1,3-sigmatropic shift of the proton. |
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