| Abstract: | Polymer blend technology has been one of the most investigated areas in polymer science in the past 3 decades. The one area of polymer blends that has been virtually ignored involves simple emulsion blends, although several articles have recently appeared that address film formation and mechanical characteristics. In this study, we investigated the mechanical property behavior of emulsion blends composed of low/high‐glass‐transition‐temperature polymers (where low and high mean below and above the test temperature, respectively). The emulsions chosen for this study had similar particle sizes, and the mixtures were rheologically stable. Two conditions were chosen, a binary combination of polymers that were thermodynamically immiscible and another system that was thermodynamically miscible. The mechanical property results over the entire composition range were compared with the predictions of the equivalent box model (EBM) with the universal parameters predicted by percolation theory. An array of randomly mixed and equal‐size particles of differing moduli was expected to show excellent agreement with theory, and the emulsion blends provided an excellent experimental basis for testing the theory. For the immiscible blend, the EBM prediction for the modulus showed excellent agreement with experimental results. With tensile strength, the agreement between the modulus and theory was good if the yield strength for the higher glass‐transition‐temperature polymer was employed in comparison with the actual tensile strength. The phase inversion point (where both phases were equally continuous) was at a 0.50 volume fraction of each component (based on an analysis employing Kerner's equation), just as expected for a random mixture of equal‐size particles. © 2001 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 39: 1093–1106, 2001 |
