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| 新型脱氢松香基苯并咪唑类衍生物的合成及其氯离子识别性能 | |
| 引用本文： | 冯少波,张业,周琪,李芳耀,潘英明,陈振锋,王恒山.新型脱氢松香基苯并咪唑类衍生物的合成及其氯离子识别性能[J].化学学报,2008,66(12):1490-1496. |
| 作者姓名： | 冯少波 张业 周琪 李芳耀 潘英明 陈振锋 王恒山 |
| 作者单位： | 1. 广西师范大学化学化工学院,桂林,541004 2. 桂林师范高等专科学校化学与工程技术系,桂林,541004 3. 桂林医学院药学院,桂林,541004 |
| 基金项目： | 国家自然科学基金 , 广西高校百名中青年学科带头人项目 , 广西自然科学基金 |
| 摘 要： | 以脱氢松香酸甲酯为原料, 经溴代、双硝化、还原、关环等步骤合成了五个新型脱氢松香基苯并咪唑类衍生物(6a～6e). 其结构用1H NMR和13C NMR进行了确证. 对6a～6e进行了阴离子识别研究, 并对其结构与氯离子识别能力的关系进行了讨论. |
| 关 键 词： | 脱氢松香酸甲酯 苯并咪唑衍生物 合成 荧光 氯离子识别 |
| 收稿时间： | 2007-8-28 |
| 修稿时间： | 2007年8月28日 |
Synthesis of Novel Dehydroabietyl Skeleton Bearing Benzimidazole Derivatives and Their Chloride Ion Recognition |
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| FENG,Shao-Bo,ZHANG,Ye,ZHOU,Qi,LI,Fang-Yao,PAN,Ying-Ming,CHEN,Zhen-Feng,WANG,Heng-Shan.Synthesis of Novel Dehydroabietyl Skeleton Bearing Benzimidazole Derivatives and Their Chloride Ion Recognition[J].Acta Chimica Sinica,2008,66(12):1490-1496. | |
| Authors: | FENG Shao-Bo ZHANG Ye ZHOU Qi LI Fang-Yao PAN Ying-Ming CHEN Zhen-Feng WANG Heng-Shan |
| Institution: | (a College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004) (b Department of Chemistry and Engineering Technology, Guilin Normal College, Guilin 541004) (c College of Pharmacy, Guilin Medical University, Guilin 541004) |
| Abstract: | Five novel dehydroabietyl skeleton bearing benzimidazole derivatives 6a～6e were synthesized through several steps such as bromation, dinitration, reduction and cyclization by using methyl dehydroabietate as a starting material. The title compounds were characterized by 1H NMR and 13C NMR. The abilities of anion recognition by these benzimidazole derivatives have been investigated. Then the relationships between the structures and the abilities of chloride ion recognition by such dehydroabietyl skeleton bearing benzimidazole derivatives were discussed. |
| Keywords: | methyl dehydroabietate benzimidazole synthesis fluorescence recognition of chloride ion |
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