| 电化学方法构筑直结型卟啉高分子 |
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| 引用本文： | 吴飞鹏,濑川浩司. 电化学方法构筑直结型卟啉高分子[J]. 化学学报, 2000, 58(1): 122-126 |
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| 作者姓名： | 吴飞鹏 濑川浩司 |
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| 作者单位： | [1]中国科学院感光化学研究所 [2]东京大学综合文化研究科 |
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| 基金项目： | 国家自然科学基金(29604008)资助项目 |
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| 摘 要： | 利用电化学方法成功地合成了不含其它连接基团的卟啉高分子,循环伏安图谱中发现该高分子在电极上的沉积为紧密型沉积,所得产物的紫外-可见吸收光谱表明相邻的卟啉环在该高分子链中均成平面直角结构,FT-IR图谱表明卟啉环之间是通过C-C键在meso位上相连,质谱图证明该高分子的链长可以达到13个卟啉环以上。
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| 关 键 词： | 卟啉 功能性高聚物 电解聚合 循环伏安法 付里叶变换 红外分光光度法 质谱法 |
| 修稿时间： | 1999-01-14 |
Construction of meso-linked porphyrin polymers via electrochemical oxidative coupling |
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| Wu Fei-PangSegawa Hiroshi. Construction of meso-linked porphyrin polymers via electrochemical oxidative coupling[J]. Acta Chimica Sinica, 2000, 58(1): 122-126 |
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| Authors: | Wu Fei-PangSegawa Hiroshi |
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| Affiliation: | Wu Fei-Pang
(Institute of Photographic Chemistry, The Chinese Academy of Sciences, Beijing, 100101
CREST, Japan Science and Technology Corporation)Segawa Hiroshi
(General Study of Arts and Sciences,The University of Tokyo; PRESTO, Japan Science and Technology Corporation) |
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| Abstract: | 5,15- bis - (3,5-di- tert - butylphenyl) porphyrin zinc and copper complexes were polymerized through electrochemical oxidation. The absorption spectra of the resultant polymers exhibit exciton coupling band in either solid state or solution. FT - IR spectra confirm that the porphyrin rings are connected to each other via a single C-C bond at the meso position. Mass spectra clearly show that the repeat units of porphyrin ring in the polymeric chain of poly - ZnBBPP are more than 13. |
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| Keywords: | electrolytic polymerization porphyrin metal complexes perphyrin polymer functional polymer |
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