Unprecedented intermolecular aldol-type condensation involving CH-acid and the nitro group |
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| Authors: | N V Moskalev M I Tartynova |
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| Institution: | (1) Tomsk Polytechnical University, 30 prosp. Lenina, 634004 Tomsk, Russian Federation;(2) Siberian State Medical University, 2 Moskovsky trakt, 634050 Tomsk, Russian Federation |
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| Abstract: | The first evidence that α-acylnitrone is an intermediate in the base-promoted reaction of 4-nitro-N,N-diethylaniline with aceptophenome to give an enaminoketone was obtained.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1645–1647, August, 1998. |
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| Keywords: | methyl ketones mononitroarenes α -acylnitrone nucleophilic addition to the ritro group |
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