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Facile synthesis of functionalised spiroethers via radical cyclisations
Affiliation:1. College of Pharmacy, Chungbuk National University, Cheongju 362-763, Republic of Korea;2. Eco-friendly Material Research Center, Korea Research Institute of Bioscience and Biotechnology, Jeonbuk 580-185, Republic of Korea;3. College of Life Sciences and Biotechnology, Korea University, Seoul 136-713, Republic of Korea;1. Department of Biochemistry, University of Zurich, Winterthurerstrasse 190, CH-8057, Zurich, Switzerland;2. Department of Pathology, Shanghai University of Traditional Chinese Medicine, Cailun Road 1200, Pudong District, Shanghai, China;1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova 28, Moscow, 119991, Russia;2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky prospect 31, Moscow, 119991, Russia;3. Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1–3, Moscow, 119991, Russia;1. Chemistry Department, Taras Shevchenko National University of Kyiv, Lva Tolstoho Street 12, Kyiv, 01033, Ukraine;2. Enamine Ltd., Chervonotkatska Street 78, Kyiv, 02660, Ukraine;3. SSI “Institute for Single Crystals”, National Academy of Sciences of Ukraine, 60 Lenina ave., Kharkiv, 61001, Ukraine;4. Department of Inorganic Chemistry, V. N. Karazin Kharkiv National University, 4 Svobody sq., Kharkiv, 61202, Ukraine;1. Department of Chemistry, Universidade Federal de Minas Gerais, Belo Horizonte, Minas Gerais 31270-901, Brazil;2. Aquaculture-Veterinay School, Universidade Federal de Minas Gerais, Belo Horizonte, Minas Gerais 31270-901, Brazil;3. Department of Biochemistry and Molecular Biology, Universidade Federal de Viçosa, Minas Gerais 36570-900, Brazil
Abstract:
Alcohols bearing suitable chains for radical initiation are smoothly condensed with cyclic β-diketones to afford systems which undergo radical cyclisation to give various spiroether products.
Keywords:
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