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First Heck reaction with arenediazonium cations with recovery of Pd-triolefinic macrocyclic catalyst
Authors:Masllorens Judit  Moreno-Mañas Marcial  Pla-Quintana Anna  Roglans Anna
Affiliation:Department of Chemistry, Universitat de Girona, 17071-Girona, Spain.
Abstract:
The air- and moisture-stable phosphine-free palladium(0) complex 1 is a highly active and recoverable catalyst for Heck olefination of aryl diazonium tetrafluoroborates. The reactions were performed under aerobic conditions at room temperature to give the coupling products in excellent yields. [reaction: see text]
Keywords:
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