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X-ray Structure of Bis(salicylidene)-p-diaminobenzene
作者姓名:ZHANG  Shu-sheng~
基金项目:国家自然科学基金,山东省自然科学基金,the Outstanding Adult-young Scientific Research Encouraging Foundation of Shan-dong Province
摘    要:IntroductionThe interactions between molecules involvingaromatic ring systems are of interest because oftheir effects on the structures and aggregation ofimportant biomolecules,on template efficiency in avariety of organic reactions,and on the solid statestructures of a variety oforganic molecules1] .Con-sistent are the analysis results of more than 2 0 0phenylalanine- phenylalanine interactions in thecrystal structures of various proteins,which leadsto the following conclusions.( 1 ) Direct …

关 键 词:西氟碱  二(亚水杨基)-p-苯二胺  氢键  晶体结构  X射线晶体学
收稿时间:2003-07-29

X-ray Structure of Bis(salicylidene)-p-diaminobenzene
ZHANG Shu-sheng.X-ray Structure of Bis(salicylidene)-p-diaminobenzene[J].Chemical Research in Chinese University,2004,20(5):562-564.
Authors:ZHANG Shu-sheng  YE Su-juan  ZHANG Tong  LI Xue-mei
Institution:College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China
Abstract:The crystal and molecular structures of Schiff base bis (salicylidene)-p-diaminobenzene were determined by X-ray crystallography. It crystallized in a monoclinic system with space group P2 (1)/c, lattice parameters a=1.4649(3) nm, b=0.45770(9) nm, c=1.2241(2) nm, α=γ=90.00°, β=112.07 (3)°, V=0. 7606(3) nm3, and Z=4. The crystal structure of the title compound is composed of discrete monomeric molecule of (C6HD (NCC6H4OH)2 which is planar. The intermolecular hydrogen bonds make the compound steady.
Keywords:Schiff base  Salicylidene  Hydrogen bond
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