| 洗涤剂用沸石的钙离子交换性能的研究 |
| |
| 引用本文： | 傅乐峰,王仰东,刘杨,董家禄,须沁华,吴璟.洗涤剂用沸石的钙离子交换性能的研究[J].无机化学学报,2000,16(1):123-126. |
| |
| 作者姓名： | 傅乐峰 王仰东 刘杨 董家禄 须沁华 吴璟 |
| |
| 作者单位： | 南京大学化学化工学院,南京,210093 |
| |
| 基金项目： | 国家863计划资助项目!(715 06) |
| |
| 摘 要： | 作为洗涤剂助剂,沸石的主要作用是通过离子交换降低水中的钙镁离子浓度、软化洗涤用水以提高洗涤剂中的表面活性剂的洗涤效率。因此,沸石对钙镁离子交换容量的大小和交换速率的快慢是评价洗涤用沸石的重要质量指标［１，２］。目前,使用最多的沸石类助剂为ＮａＡ沸石。为了弥补ＮａＡ型沸石镁离子交换能力的不足,先后又出现了Ａ、Ｘ型沸石混合使用［３］、高铝Ｘ型沸石(ＭＡＸ)［４～５］和高铝Ｐ型沸石(ＭＡＰ)等技术［１，２］。ＭＡＸ型和ＭＡＰ型沸石与ＮａＡ型沸石一样具有最小的硅铝比(ＳｉＯ２／Ａｌ２Ｏ３＝２)。因此,这三种沸石的…
|
| 关 键 词： | 沸石 钙离子交换 交换性能 洗涤剂助剂 |
| 收稿时间： | 1999/5/24 0:00:00 |
| 修稿时间： | 1999/9/14 0:00:00 |
Study on Calcium Ion exchange Behavior of Zeolites Used in Detergent |
| |
| FU Le-Feng,WANG Yang-Dong,LIU Yang,DONG Jia-Lu,XU Qin-Hua and WU Jing.Study on Calcium Ion exchange Behavior of Zeolites Used in Detergent[J].Chinese Journal of Inorganic Chemistry,2000,16(1):123-126. |
| |
| Authors: | FU Le-Feng WANG Yang-Dong LIU Yang DONG Jia-Lu XU Qin-Hua and WU Jing |
| |
| Institution: | Chemistry Department Nanjing University, Nanjing 210093,Chemistry Department Nanjing University, Nanjing 210093,Chemistry Department Nanjing University, Nanjing 210093,Chemistry Department Nanjing University, Nanjing 210093,Chemistry Department Nanjing University, Nanjing 210093 and Chemistry Department Nanjing University, Nanjing 210093 |
| |
| Abstract: | Calcium ion exchange behavior of Zeolites used in detergent such as NaA, NaX and NaP was studied by Ion Selective Electrode Method (ISE). The linear relationship between calcium ion exchange capacity and framework aluminum content of zeolite NaX was found, and the effects of exchange temperature, concentration of zeolite and other cations on calcium ion exchange behavior were also investigated. The sequence of the calcium ion exchange selectivity of zeolite MAP, NaA and NaP was determined. The framework structure of zeolite NaA, NaX and NaP significantly influence the cation exchange behavior of these three zeolites. |
| |
| Keywords: | detergent zeolites calcium ion exchange |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
