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Non-isothermal kinetics of reactions whose activation energy depends on the degree of conversion
Authors:P. Budrugeac and E. Segal
Affiliation:

a ICPE - Research and Design Institute for Electrical Engineering, Splaiul Unirii, Nr. 313, Sector 3 Bucharest 74.204 Romania

b Department of Physical Chemistry, Faculty of Chemistry, University of Bucharest, Bd. Republicii, Nr. 13 Bucharest Romania

Abstract:A procedure for evaluating the non-isothermal kinetic parameters of reactions for which the activation energy depends on the degree of conversion is suggested. The procedure has been applied to the dehydration of calcium oxalate monohydrate and to the thermal degradation of poly(vinyl chloride) (PVC) and polychloroprene rubber.
Keywords:Activation energy   Non-isothermal kinetics   Thermal degradation
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