Thermodynamic studies on the ferroelectric phase transition in neutron irradiated (LixK1−x)2SO4 crystals at high temperature |
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Authors: | M. E. Kassem A. M. El-Khatib E. A. Ammar M. M. Denton |
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Affiliation: | 1. International Centre for Theoretical Physics, Trieste, Italy 2. Physics Department, Faculty of Science, Alexandria University, Alexandria, Egypt
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Abstract: | Thermodynamic studies of (LixK1?x)2SO4, LKS, mixed crystals have been made in the concentration range (x=0.1, 0.2, ...,x=0.5). The thermal behaviour has been investigated by differential thermal analysis, DTA, and differential scanning calorimeter, DSC, in the vicinity of high temperature phases. Also, the effect of the thermal neutron irradiations on the thermal properties of mixed crystals was studied. The results showed a change in the transition temperatureT c, as well as the value of specific heatC p at transition temperature, due to the change of stoichiometric ratio and radiation doses. The change of enthalpy and entropy of mixed crystals have been estimated numerically. |
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